CBSE Class 12 d- and f-Block Elements PYQs Analysis (2021-2025)

Based on detailed analysis of last 5 years' papers. Perfect for 2026 Boards prep!

Key Trends

Most Important and Repeated Questions

Question Example Type/Marks Years Repeated Notes
Calculate spin-only magnetic moment for Fe²⁺ (d⁶, 4 unpaired e⁻). Is it paramagnetic? Numerical (2 marks) 2021 Term 2, 2022, 2023, 2024, 2025 Repeated 5x; μ ≈ 4.9 BM.
Why do transition metals show variable oxidation states? Element with max states in 3d series? Short Answer (2 marks) 2022, 2023, 2024, 2025 Repeated 4x; Mn (+2 to +7).
Explain KMnO₄ as oxidizing agent in acidic medium. Reaction with Fe²⁺/oxalic acid (balanced eq.). Reasoning/Equation (3 marks) 2021 Term 1, 2022, 2023, 2025 Repeated 4x; MnO₄⁻ + 8H⁺ + 5e⁻ → Mn²⁺.
What is lanthanoid contraction? Two consequences (e.g., similar radii Zr-Hf, basicity decrease). Short Answer (3 marks) 2022, 2023, 2024, 2025 Repeated 4x; Poor 4f shielding.
Compare K₂Cr₂O₇ and KMnO₄ as oxidants. Reaction with KI in acidic medium. Comparison (2 marks) 2023, 2024, 2025 Repeated 3x; Cr₂O₇²⁻ + 14H⁺ + 6e⁻ → 2Cr³⁺.
Assertion: Sc³⁺ is colorless while Ti³⁺ is colored. Reason: d⁰ vs d¹ configuration. Assertion-Reason (1 mark) 2022, 2024, 2025 Repeated 3x; d-d transition.
Why are transition metals good catalysts? Example (e.g., Fe in Haber, V in Contact). Reasoning (2 marks) 2021 Term 2, 2023 Repeated 2x; Variable states.
Compare lanthanoids and actinoids (oxidation states, size, reactivity). Short Answer (2 marks) 2024, 2025 Repeated 2x; Actinoids more reactive.
MCQ: Magnetic nature of [Cu²⁺] (d⁹): (a) Diamagnetic (b) Paramagnetic. MCQ (1 mark) 2023, 2025 Repeated 2x; (b).
Case-based: Explain color in d-block ions. Calculate μ for Ni²⁺ (d⁸, 2 unpaired). Case-Based (4 marks) 2022, 2025 Repeated 2x; μ ≈ 2.83 BM.

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